Badania efektywności procesu ekstrakcji miedzi

• Autorzy: Ryszard Cierpiszewski

Warianty tytułu

Investigation into the Efficiency of Copper Extraction Process.

• Języki publikacji: PL

Abstrakty

W pracy zbadano i omówiono właściwości kilku grup związków chemicznych: określono wpływ składu fazy organicznej oraz struktury stosowanych ekstrahentów na szybkość ekstrakcji miedzi z roztworów wodnych wykorzystując w badaniach związki modelowe o ściśle zdefiniowanej budowie oraz ekstrahenty handlowe. Podjęto także próbę oszacowania kosztów otrzymywania miedzi metoda hydrometalurgiczną z roztworów chlorkowych.

EN

The rate of copper(II) extraction with hydrophobic derivatives of model extractants and with commercial preparations was studied. The following groups of compounds were used: aromatic hydroxyoximes, alkanal oximes, bis-hydroxyoximes, p-diketons, and hydrophobic derivatives of pyridine carboxylic acid amides and esters. Extraction rates obtained using the extractants investigated indicate that differences observed are not merely due to the different hydrophobicities of the compounds investigated or to differences in their surface excess. More important in many cases is the interfacial orientation of the extractant molecules, as confirmed by differences in the extraction rates in systems containing a solvating solvent and a non-solvating one. Amicellar system was used to discuss the mechanism and rate of copper(II) extraction in a "classic" liquid-liquid extraction. It was found that differences in the complexing rates observed for extractants with different hydrophobicities result, principally, from their interfacial behaviors. The favorable effect of aliphatic a-hydroxyketoxime on the rate of copper(II) extraction with aromatic hydroxyoximes was verified by micellar system studies. The equilibrium of copper(II) extraction from chloride solutions was investigated, using solvating extractants and a chelating one. A constant water phase activity was employed to prevent the water phase from affecting the results obtained. The solvating extractants are better copper extractants in higher chloride ion concentration ranges. The rate of extraction was investigated using a mixture of a solvating and a chelating extractant and a mixture comprising a solvating extractant and a modifier. The rate of extraction was observed to fall after introducing an additional substance in each of the systems investigated. The rate decline observed was mainly due to the interfacial area being blocked by the modifier or by the chelating ex-tractant. Copper production costs by the hydrometallurgical and pyrometallurgical methods were compared and major environmental hazards involved in copper production were pointed out. (original abstract)

Słowa kluczowe

PL

Towaroznawstwo przemysłowe; Chemia; Przemysł chemiczny; Produkcja miedzi; Przegląd literatury

EN

Industrial commodities; Chemistry; Chemical industry; Production of copper; Literature review

• Czasopismo: Prace Habilitacyjne / Akademia Ekonomiczna w Poznaniu
• Rocznik: 2003
• Numer: nr 8
• Strony: 166

Twórcy

autor

Ryszard Cierpiszewski

Bibliografia

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