Ocena przydatności wielkocząsteczkowych amin alifatycznych do ekstrakcji kwasów jabłkowego i fumarowego

• Autorzy: Zbigniew Garncarek , Barbara Garncarek

Warianty tytułu

Extraction of Malic and Fumaric Acids with High Molecular Amine Extractants

• Języki publikacji: PL

Abstrakty

Ekstrahowano kwasy jabłkowy i fumarowy przy użyciu wielkocząsteczkowych amin (trójoktyloaminy, Amberlite LA-1 i LA-2) rozpuszczonych w ksylenie oraz nitrobenzenie. Wykazano znaczący wpływ rodzaju rozcieńczalnika na wartości stałych równowagi tworzonych kompleksów kwas-amina. Ustalono występowanie kompleksów kwas-amina w szerokim zakresie proporcji od 1:1 do 3:2. Na podstawie uzyskanych wyników stwierdzono, że najbardziej odpowiednim układem do selektywnej ekstrakcji kwasu jabłkowego jest anionit Amberlite LA-2 rozpuszczony w nitrobenzenie.(abstrakt oryginalny)

EN

The paper deals with the malic and fumaric acid extraction by trioctylamine, Amberlite LA-1 and LA-2 dissolved in xylene and nitrobenzene. The strong influence of diluents on the mathematically determined equilibrium constants is shown. The equilibrium complexation constants for ratios from 1:1 to 3:2 have been estimated. Taking into account the extraction result, it is concluded that the most appropriate system of selective extraction, which permits to separate successfully malic from fumaric acid, corresponds to Amberlite LA-2 dissolved in nitrobenzene.(original abstract)

Słowa kluczowe

PL

Biotechnologia

EN

Biotechnology

• Czasopismo: Nauki Inżynierskie i Technologie / Uniwersytet Ekonomiczny we Wrocławiu
• Rocznik: 2012
• Numer: nr 4 (7)
• Strony: 41--53

Twórcy

autor

Zbigniew Garncarek

• Uniwersytet Ekonomiczny we Wrocławiu

autor

Barbara Garncarek

• Uniwersytet Ekonomiczny we Wrocławiu

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