Structural Investigations on Mono- and Diperchlorates of Sparteine and Its Stereoisomers by ¹³C-NMR Spectroscopy

• Autorzy: Jerzy Skolik , Halina Podkowińska

Warianty tytułu

Spektroskopowe badania ¹³C-NMR struktury mono- i dinadchloranów sparteiny i jej stereoizomerów

• Języki publikacji: EN

Abstrakty

Przeprowadzono analizę widm ¹³C-NMR mono- i dinadchloranów α-izosparteiny, sparteiny i Β-izosparteiny. Korzystając z pomocy danych spektralnych dla związków modelowych, pochodnych częściowo deuterowanych i widm "off resonance" przyporządkowano sygnały w widmach badanych związków, a także określono konformację mono- i dikationów. Dla kationów, które posiadają identyczną konformację jak odpowiednia wolna zasada wyliczono efekty protonowania. Przeprowadzono dyskusję czynników wywierających istotny wpływ na przesunięcia chemiczne w kationach soli oraz odpowiedzialnych za efekty protonowania. (abstrakt oryginalny)

Słowa kluczowe

EN

Organic chemistry; Chemical compounds; Commodity science

PL

Chemia organiczna; Związki chemiczne; Towaroznawstwo

• Czasopismo: Zeszyty Naukowe. Seria 1 / Akademia Ekonomiczna w Poznaniu
• Rocznik: 1991
• Numer: nr 198 Prace z zakresu towaroznawstwa i chemii
• Strony: 109--125

Twórcy

autor

Jerzy Skolik

autor

Halina Podkowińska

Bibliografia

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