Nanocomposites with Polyhedral Oligomeric Silsesquioxane Nanofillers - Characterization of Morphology, Thermal and Mechanical Properties

• Autorzy: Arkadiusz Niemczyk , Katarzyna Dziubek , Robert Korach , Marek Grzymek , Michał Dutkiewicz
• Języki publikacji: EN

Abstrakty

EN

High-density polyethylene nanocomposites with hydroxy-hepta(iso-butyl)-octasilsesquioxane (POSS-(i-Bu)7OH) and hydroxy-hepta(iso-octyl)-octasilsesquioxane (POSS-(i-Oct)7OH) as nanofillers were prepared by melt blending. The morphological, thermal and mechanical properties as well as processability of obtained nanocomposites were characterized. POSS nanofillers were homogenously dispersed in polymeric matrix. High compatibility between nanofiller and polymer induced enhanced thermal stability, Charpy impact strength and melt flow rate for composite materials. POSS particles acted also as a nucleating agent for polyethylene crystallization in the nanocomposite. (original abstract)

Słowa kluczowe

EN

Polymer composites; Polymers; Nanotechnology

PL

Kompozyty polimerowe; Polimery; Nanotechnologia

• Czasopismo: Acta Innovations
• Rocznik: 2016
• Numer: nr 21
• Strony: 5--12

Twórcy

autor

Arkadiusz Niemczyk

• Faculty of Chemistry, University of Opole

autor

Katarzyna Dziubek

• Faculty of Chemistry, University of Opole

autor

Robert Korach

• Faculty of Chemistry, University of Opole

autor

Marek Grzymek

• Faculty of Chemistry, University of Opole

autor

Michał Dutkiewicz

• Centre for Advanced Technologies, Adam Mickiewicz University

Bibliografia

• I.-Y. Jeon, J.-B. Baek, Nanocomposites Derived from Polymers and Inorganic Nanoparticles, Materials 3 (2010) 3654-3674.
• T. Krasia-Christoforou, Organic-Inorganic Polymer Hybrids: Synthesis Strategies and Applications, in: C.-S. Kim, C. Randow, T. Sano (Eds.), Hybrid and Hierarchical Composite Materials, Springer International Publishing, Switzerland, 2015, ss. 11-64.
• C. Sanchez, B. Julian, P. Belleville, M. Popall, Applications of hybrid organic-inorganic nanocomposites, J. Mater. Chem. 15 (2005) 3559-3592.
• D.R. Paul, L.M. Robeson, Polymer nanotechnology: Nanocomposites, Polymer 49 (2008) 3187-3204.
• R.H. Baney, M. Itoh, A. Sakakibara, T. Suzuki, Silsesquioxanes, Chem. Rev. 95 (1995) 1409-1430.
• D.B. Cordes, P.D. Lickiss, F. Rataboul, Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes, Chem. Rev. 110 (2010) 2081-2173.
• C. Hartmann-Thompson, Polyhedral oligomeric silsesquioxanes in electronics and energy applications, in: C. Hartmann-Thompson (Ed.), Applications of polyhedral oligomeric silsesquioxanes, in: J. Matisons (series Ed.), Advances in Silicon Science 3, Springer Science & Business Media BV, 2011, ss. 247-325.
• K. Tanaka, Y. Chujo, Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS), J. Mater. Chem. 22 (2012) 1733-1746.
• K.G. Williams, S.P. Gido, E.B. Coughlin, Polymers and copolymers containing covalently bonded polyhedral oligomeric silsesquioxanes moieties. in: C. Hartmann-Thompson, (Ed.), Applications of polyhedral oligomeric silsesquioxanes. in: J. Matisons (series Ed.), Advances in Silicon Science 3, Springer Science & Business Media BV, 2011, ss. 167-207.
• E. Ayandele, B. Sarkar, P. Alexandridis, Polyhedral oligomeric silsesquioxane (POSS)-containing polimer nanocomposites, Nanomater. 2 (2012) 445-475.
• G. Li, L. Wang, H. Ni, J.C.U. Pittman, Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: a review, J. Inorg. Organomet. Polym. 11 (2001)123-154.
• S.W. Kuo, F.C. Chang, POSS related polymer nanocomposites, Prog. Polym. Sci. 36 (2011) 1649-1696.
• T. Pisuchpen, V. Intasanta, V.P. Hoven, Highly porous organic-inorganic hybrid fiber from copolymers of styrene and polyhedral oligomeric silsesquioxane-derived methacrylate: syntheses, fiber formation and potential modification, Eur. Polym. J. 60 (2014) 38-48.
• A. Fina, D. Tabuani, A. Frache, G. Camino, Polypropylene-polyhedral oligomeric silsesquioxanes (POSS) nanocomposites, Polymer 46 (2005) 7855-7866.
• A. Niemczyk, K. Dziubek, B. Sacher-Majewska, K. Czaja, M. Dutkiewicz, B. Marciniec, Study of thermal properties of polyethylene and polypropylene nanocomposites with long alkyl chain substituted POSS fillers, J. Therm. Anal. Calorim. 125 (2016) 1287-1299.
• A. Niemczyk, K. Dziubek, K. Czaja, R. Szatanik, M. Szołyga, M. Dutkiewicz, B. Marciniec, Polypropylene/polyhedral oligomeric silsesquioxane nanocomposites - study of free volumes, crystallinity degree and mass flow rate, Polimery-W 61 (2016) 610-615.
• F. Carniato, E. Boccaleri, L. Marchese, A. Fina, D. Tabuani, G. Camino, Synthesis and characterisation of metal isobutylsilsesquioxanes and their role as inorganic-organic nanoadditives for enhancing polymer thermal stability, Eur. J. Inorg. Chem. 4 (2007) 585-591.
• A. Fina, H.C.L. Abbenhuis, D. Tabuani, A. Frache, G. Camino, Polypropylene metal functionalized POSS nanocomposites: a study by thermogravimetric analysis, Polym. Degrad. Stab. 91 (2006) 1064-1070.
• M. Pracella, D. Chionna, A. Fina, D. Tabuani, A. Frache, G. Camino, Polypropylene-POSS nanocomposites: morphology and crystallization behavior, Macromol. Symp. 234 (2006) 59-67.
• M. Barczewski, T. Sterzyński, M. Dutkiewicz, Thermo-rheological properties and miscibility of linear lowdensity polyethylene-silsesquioxane nanocomposites, J. Appl. Polym. Sci. 132 (2015) 42825.
• N.L. Dias Filho, H.A. De Aquino, G. Pires, L. Caetano, Relationship between the Dielectric and Mechanical Properties and the Ratio of Epoxy Resin to Hardener of the Hybrid Thermosetting Polymers, J. Brazil. Chem. Soc. 17 (2006) 533-541.
• B. Wunderlich, G. Czornyj, A study of equilibrium melting of polyethylene, Macromolecules 10 (1977) 906-913.
• J.V. Gulmine, P.R. Janissek, H.M. Heise, L. Akcelrud, Polyethylene characterization by FTIR, Polym. Test. 21 (2002) 557-563.
• C. Vasile, M. Pascu, Practical Guide to Polyethylene, Rapra Technology Limited, Shawbury, Shrewsbury, Shropshire, 2005.
• R. Al-Oweini, H. El-Rassy, Synthesis and characterization by FTIR spectroscopy of silica aerogels prepared using several Si(OR)4 and R''Si(OR')3 precursors, J. Mol. Struct. 919 (2009) 14-145.
• A. Fina, D. Tabuani, F. Carniato, A. Frache, E. Boccaleri, G. Camino, Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation, Thermochim. Acta 440 (2006) 36-42.
• T. Glaskova, M. Zarrelli, A. Aniskevich, M. Giordano, L. Trinkler, B. Berzina, Quantitative optical analysis of filler dispersion degree in MWCNT-epoxy nanocomposite, Compos. Sci. Technol. 72 (2012) 477-481.
• F.X. Perrin, D.M. Panaitescu, A.N. Frone, C. Radovici, C. Nicolae, The influence of alkyl substituents of POSS in polyethylene nanocomposites, Polymer 54 (2013) 2347-2354.
• M. Joshi, B.S. Butola, Studies on nonisothermal crystallization of HDPE/POSS nanocomposites, Polymer 45 (2004) 4953-4968.
• X. Huang, L. Xie, P. Jiang, G. Wang, Y. Yin, Morphology studies and ac electrical property of low density polyethylene/octavinyl polyhedral oligomeric silsesquioxane composite dielectrics, Eur. Polym. J. 45 (2009) 2172-2183.
• E.L. Heeley, D.J. Hughes, Y.E. Aziz, P.G. Taylor, A.R. Bassindale, Morphology and crystallization kinetics of polyethylene/long alkyl-chain substituted Polyhedral Oligomeric Silsesquioxanes (POSS) nanocomposite blends: A SAXS/WAXS study, Eur. Polym. J. 51 (2014) 45-56.
• A.N. Frone, F.X. Perrin, C. Radovici, D.M. Panaitescu, Influence of branched or un-branched alkyl substitutes of POSS on morphology, thermal and mechanical properties of polyethylene. Compos. Part B Eng. 50 (2013) 98-106.
• B.B. Marosfoi, A. Szabó, Gy. Marosi, D. Tabuani, G. Camino, S. Pagliari, Thermal and spectroscopic characterization of Polypropylene-carbon nanotube composites, J. Therm. Anal. Calorim. 86 (2006) 669-673.
• S.D.C. Guerreiro, I.M. Joao, L.E.P. Real, Evaluation of the influence of testing parameters on the melt flow index of thermoplastics, Polym. Test. 31 (2012) 1026-1030.
• L. Delva, K. Ragaert, J. Degrieck, L. Cardon, The Effect of Multiple Extrusions on the Properties of Montmorillonite Filled Polypropylene, Polymers 6 (2014) 2912-2927.
• M. Joshi, B.S. Butola, G. Simon, N. Kukaleva, Rheological and Viscoelastic Behavior of HDPE/Octamethyl-POSS Nanocomposites, Macromolecules 39 (2006) 1839-1849.