PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
2019 | 2(2) Selected Aspects of Production Engineering in Management and Materials Engineering | 289--300
Tytuł artykułu

Peculiarities of Alloying Effect on the Eutectic Cementite Behavior Under Hot Rolling

Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Currently, cast iron remains one of the major modern casting materials in metallurgy and machine-building industry and is sure to take the lead in the future. Chilled cast iron has high hardness and wear resistance due to a large number of carbide phases in its structure. However, low ductility and impact hardness essentially limit its applicability in terms of processing. Hot plastic working, under which the eutectic net crushing is observed, appears to be one of the most effective means of the eutectic alloy products shape and microstructure transformation. Chilled cast iron properties fundamentally improve after hot plastic working: ductility, strength and impact hardness increase by 2-3 times on retention of the high hardness factor. Chilled cast iron ductility increase can be attained when using phase transformations in eutectic cementite under lean alloying with carbide forming elements. The purpose of the paper is to study alloying effect on the chilled cast iron ductility as well as eutectic cementite behavior under hot rolling. In the paper hardening and softening of the structural components in chilled cast iron under hot working have been studied. The deformation texture forming in eutectic cementite under hot rolling has been revealed, which is connected with the dynamic softening and depends on the degree and the nature of its alloying. The mechanism and regularities of the phase transformation effect in cementite on its behavior under plastic deformation and on the alloys ductility in general have been studied. In cementite chromium alloying initiates processes, that can be characterized as the pre-precipitation stage of the new phases, and this way it contributes to the cast iron ductility reduction and embrittles cementite. Carbide transformation, that occurs in eutectic cementite under alloying with vanadium, stimulates softening of the alloy and increases its ductility level. Moreover, the multiple glide planes {130},{011},{112} in cementite have been determined. It has been found out, that in supersaturated cementite vanadium carbides precipitation stimulates the extra glide plane {111} occurrence under hot rolling. The essence of the carbide transformation phenomenon is that under hot working there occurs the lubricating effect at the transition of the metastable iron carbide condition, which is strengthened with vanadium supersaturation and mechanical hardening, to a more stable condition due to precipitation of the proeutectoid constituents on the one hand, and because of the dynamic softening processes on the other hand. At that, the autocatalyticity effect is observed: there is precipitation of carbides with hardening and softening, similar to the processes that arise as a result of the superplastic effect induced by phase transformations. (original abstract)
Twórcy
  • The National Metallurgical Academy, Ukraine
  • Dnipropetrovsk National University of Railway Transport, Ukraine
Bibliografia
  • Andrews K., Dyson D., Keown S. (1971). Elektronogrammy i ikh interpretatsiya [Electron-diffraction patterns and their interpretation- Moskow: Mir, p. 256.
  • Barnes, A. J.Superplastic forming 40 years and still growing (2006) Conference: Materials Science and Technology Conference and Exhibition. Journal of Materials Engineering and Performance. Volume 16 , Issue 4, pp. 440-454. Published: AUG 2007. DOI: 10.1007/s11665-007-9076-5
  • Bedolla-Jacuinde, A.; Guerra, F. V.; Mejia, I. (2015). Abrasive wear of V-Nb-Ti alloyed high-chromium white irons. Conference: 20th International Wear of Materials Conference (WOM) Location: Toronto, CANADA Date: APR 12-16, Volume: 332 pp. 1006-1011.
  • Bedolla-Jacuinde, A; Correa, R; Quezada, JG; et al. (2005). Effect of Titanium on the As-Cast Microstructure of a 16%Chromium White Iron. Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing. Volume 398, Issue 1-2, pp. 297-308. Available at: https://doi.org/10.1016/j.msea.2005.03.072.
  • Bochvar A.A. (1948). O raznykh mekhanizmakh plastichnosti v metallicheskikh splavakh [On the problem of different ductility mechanisms in metal alloys]. Izvestiia Akademii nauk SSSR. No. 5, pp. 56-58.
  • Cerri, E.; Knez, D.; Rimoldi, T.; et al. (2017) Microstructure evolution and mechanical properties of hot deformed Mg9A11Zn samples containing a friction stir processed zone. JournaL of Magnesium and Alloys. Volume 5, Issue 4, pp. 388-403 https://doi.org/10.1016/j.jma.2017.11.003.
  • Dojka, M.; Kondracki, M.; Studnicki, A.; et al. (2018). Crystallization Process of High Chromium Cast Iron with the Addition of Ti and Sr. Archives of Foundry Engineering. Volume 18, pp. 57-64.
  • Figueiredo, Roberto B.; Langdon, Terence G. (2008). Record superplastic ductility in a magnesium alloy processed by equal-channel angular pressing. Advanced Engineering Materials. Volume: 10, pp. 37-40. Available at: https://doi.org/10.1002/adem.200700315
  • Guo Erjun; Wang Lihua; Wang Liping; et al. (2009)/ Effects of RE, V, Ti and B Composite Modification on the Microstructure and Properties of High Chromium Cast Iron Containing 3% Molybdenum. Rare Metals. Volume 28, pp. 606-611.
  • Hume-Rozery W., Raynor, A.T. (1942). Journal. I.S.I. Volume145 (143), pp. 93-117.
  • Jiang, Jipeng; Li, Shibo; Li, Haolin; et al. (2017). Effect of in Situ Formed TiCx Grains on the Microstructural Modification of High Chromium White Iron/ Journal of Alloys and Compounds, Volume 726 (5), pp. 430-436. Available at: https://doi.org/10.1016/j.jallcom.2017.07.274.
  • LI, H; Wang, YM; Burdett, CF. (1991). Hot Deformation-Behavior and Ledeburite Refinement Mechanism for Hypoeutectoid Low-Alloy White CasT Irons. Materials Science and Technology. Volume 7, pp. 660-664. Available at: https://doi.org/10.1179/mst.1991.7.7.660
  • Lipson R.G., N.I. Petcy. (1940). Journal. I.S.I. Volume 142 (95), pp 79-85. Available at: http://ena.lp.edu.ua:8080/handle/ntb/15406
  • Liu, Hai-yun; Song, Zhi-liang; Cao, Qing. (2016). Microstructure and Properties of Fe-Cr-C Hardfacing Alloys Reinforced with TiC-NbC. Journal of Iron and Steel Research International. Volume 23 (3), pp. 276-280. Available at: DOI: 10.1016/S1006-706X (16)30045-0
  • Maja, M. E.; Maruma, M. G.; Mampuru, L. A.; et al. (2016). Effect of Niobium on the Solidification Structure and Properties of Hypoeutectic High-Chromium White Cast Irons. Journal of the SoutherN AfricaN Institute of Mining and Metallurgy. Volume 116, pp. 981-986. Available at:DOI: 10.17159/2411-9717/2016/v116n10a14
  • Mironova T.M., Donskaya T.R. Sidorova.A.Yu. (2012). O mekhanizmakh vliyaniya fazovykh perekhodov na povedenie evtekticheskikh karbidov pri deformirovanii [On the problem of mechanisms of phase changes effect on the eutectic carbides behavior at deformation] Visnyk Dnipropetrovskoho universytetu. Physics. Radioelectronics, 20(2), pp. 97-104.
  • Mironova T.M., Kutsova V.Z. (2009). Struktura i svoistva deformiruemykh chugunov. Dnepropetrovsk. Driant. 190 p.
  • Osipov K.A. (1949).O mekhanizme plastichnosti gomogennykh splavov pri vysokikh temperaturakh [On the problem of ductility mechanism of homogeneous alloys at high temperatures] Izvestiia Akademii nauk SSSR, no. 9,pp. 38-41.
  • Pirogova E.V. (1990) Strukturnye izmeneniya v cementite belykh chugunov pri goryachey plasticheskoy deformatsii [Structural changes in the white iron cementite under hot plastic deformation]. Composition and mechanical properties of metallic materials: collection of scientific papers. . Leningrad: L. D. Nauchnotekhnicheskoy Propagandy, pp. 85-87.
  • Presnyakov A.A. (1969) Sverkh plastichnost metallov i splavov [Superplasticity of metals and alloys] Nauka Kazakhskoy SSR, Alma-At:, p. 209.
  • Silman, G.I.; Makarenko, K.V. (2010). Some Features of Eutectic Structure Formation in Cast Iron. Metal Science and Heat Treatment, Volume 52 (7-8), pp.316-320.
  • Silman, G.I (1992).Phase-Diagram of the FE-C-V System and Its Application to Metallography of Steels and Cast Irons. Metal Science and Heat Treatment, Volume 34 (11-12), pp. 665-670.
  • Sukhanov D.A., Arhangelskiy L.B., Plotnikova N.V., Sukhanova L.N., Golikov A.Yu. (2017) White Cast Iron Plastic Deformation. Obrabotka metallov (tekhnologiya, oborudovanie, instrumenty) -Metal Working and Material Science,. 4 (77), pp. 43-54. Available at: doi: 10.17212/1994- 6309-2017-3-43-54.
  • Taran-Zhovnir, Yu.N. (1998) Stroenie evtektik i sozdanie novykh splavov evtekticheskogo tipa [Structure of eutectics and creation of new alloys of eutectic type] Modern linguistics of the XXI century. 1sted. Pohodnya, I.K.: Kyiv, Naukova dumka, pp. 176-197.
  • Taran, YN; Nizhnikovskaya, PF; Mironova, TM. (1981). Structural-Changes in Eutectics In R6M5 Steel During Hot Plastic-Deformation. Steel in the USSR. pp. 296-298.
  • Tsobkallo O.S., Latsh V. V. (1957). Rentgenograficheskiy analiz struktury alyuminiya i latuni L70 [The X-ray test of aluminium and brass Л70 structure] Izvestiia Akademii nauk SSSR, No. 3 ,pp. 28-32.
  • Wu, Zhicheng; Sandloebes, Stefanie; Rao, Jing; et al. (2018). Local Mechanical Properties and Plasticity Mechanisms in a Zn-Al Eutectic Alloy. Materials & Design. Volume 157 pp. 337-350. Available at: https://doi.org/10.1016/j.matdes.2018.07.051
  • Zhang, Jianjun; Gao, Yimin; Xing, Jiandong; et al. (2010). Effects of Forging and Heat Treatment on Microstructure and Properties of High Boron White Cast Iron. Conference: 9th International Symposium on Science and Processing of Cast Iron Location: Luxor, EGYPT Date: NOV 10-13,. Central Metallurg Res & Dev Inst. Science and processing of Cast Iron IX .Book Series: Key Engineering Materials Volume 457, pp. 225-230. Published 2011, Available at: https://doi.org/10.4028/www.scientific.net/KEM.457.225
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.ekon-element-000171592163

Zgłoszenie zostało wysłane

Zgłoszenie zostało wysłane

Musisz być zalogowany aby pisać komentarze.
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.